EnglishPaint and Varnish Processes
PAINT SECTOR TERMSCapacity:This manufacturing; It consists of mixing the coloring pigments and fillers in mixers with crushing effect.Red powder coating is usually done in ball mills or kollergang.a) Ball (Steel, porcelain or pebble) Mills:These devices are; They are cylindrical devices made of hard steel, porcelain or hard stones, such as granite, or soft plastic coating, rotating around a horizontal pivot with steel porcelain or pebble balls.In these devices, the measurements that determine the empty volume of the mill are determined.The number representing ¼ of the mill's empty interior volume (in kg if the volume is liters, in tons if in cubic meters) gives the powder paint put on a charge to the mill. Charging time is 2 hours including filling, crushing-mixing and discharging.b) Kollerganglar:These devices consist of heavy cylindrical or conical wheels that roll and roll on a solidly constructed tray in the form of cylinders or truncated cones.In these devices, the dimensions that are the basis for calculating the empty volume of the kollergang tray are determined.The number representing ¼ of the empty interior volume of the Kollergang tray (in kg if the volume is liters, in tons if in cubic meters) gives the powder paint put on the device at a charge. Charging time is 1 hour including filling, crushing-mixing and discharging.Raw Materials: (To obtain 1000 kg of product). Colorant pigments only (excluding white pigments): 9 kg.. Carbon black: 1.5 kg.. Filling materials: 92,5 kg.. Alcohol: 1 kg.
HOT VARNISH PRODUCTIONCapacity:The production of hot varnish is done in devices that have heating devices up to 2700 oC. Cooking, cooling and thinning processes can be done in the same or separate boilers.a) In fixed boilers: Filling, cooking, cooling, thinning and discharging time is accepted as 8 hours.b) In boilers that are fully closed, equipped with a motor-mixing mixer, equipped with a cooling coil or a jacket that supplies pressurized water to the cooler: This period is accepted as (4) hours. The capacity of the boilers, any of which is deficient, is calculated according to (a).c) For boilers up to 250 liters: It is assumed that 2 boilers (or 4 charges in 8 hours from each furnace) can be taken from each boiler provided that there is one fixed stove and sufficient transportation means for both boilers.Whether the heating device is sufficient, the number of hobs can be moved, the size of the boiler and the size measurements required to calculate the volumes of the boilers are determined and recorded.In addition, it is investigated whether the boiler handling device is sufficient and whether the furnaces are suitable for changing the boiler easily. Boilers are considered to be charged to 80% of their volume.Raw and Auxiliary Materials: (To obtain 100 kg of product). Synthetic resins: 35 kg.. Fats (flax, soy, Chinese tree, castor oil and vegetable oils such as fish oil): 14 kg.. Wow spirit: 15 kg.. Toluol: 5 kg.. Xylol or toluol: 24 kg.. Solvent naphtha: 5 kg.. Alcohols (excluding industrial alcohol): 10 kg.. Industrial alcohol: 1 kg.. CLEARS: 1.5 kg.. Additives: 0.5 kg.The above quantities include the average manufacturing loss.COLD VARNISH AND THINNER PRODUCTIONCapacity:Since cold varnish and thinner are generally made in very simple tools, it is considered objectionable to accept the production of these devices as capacity. Therefore, in this type of manufacturing; The figure found by adding 25% development share to the largest of the actual manufacture of the past three years is considered as capacity.In facilities that have just started operation or have no actual consumption for other reasons, the capacity is compared to similar facilities and is appreciated.
CELLULOSIC VARNISH PRODUCTIONCapacity:It is prepared in cellulosic varnish agitator and uniform closed mixers. It is assumed that it can be charged every 6 hours and it can be charged up to 80% of the volume of the mixer. In plants with a "base preparation drum" or "pre-mixer" of at least 1/4 of the volume of the mixer as an aid to the mixer, the mixer capacity is multiplied by a factor of 2. The measurements that are the basis for calculating the volume of the mixer and drum or premixer, if any, are determined and recorded. If the mixer used in the mixer is high speed, it is accepted that 3 charges can be taken in 8 hours.Raw Materials: (To obtain 100 kg of product). Nitrocellulose (dry): 19 kg.. Plasticizer: 6 kg.. Synthetic resin: 6 kg.. Alkyd resin (100%): 6 kg.. Ketones and ketone alcohols: 14 kg.. Esters: 15 kg.. Glycol ethers: 5 kg.. Alcohols (excluding industrial alcohol): 5 kg.. Industrial alcohol: 3 kg.. Toluol: 18 kg.. Xylol or toluol: 11 kg.Also;. Polyethylene wax: 0,5 kg.. Zinc stearate: 1 kg.These amounts include the average manufacturing loss.CELLULOSIC PAINTS-PLASTIC- EMULSION PAINTS CONSTRUCTION PAINTS AND INDUSTRIAL PAINTS MANUFACTURINGCapacity:The manufacture of cellulosic, plastic-emulsion- construction and industrial paints consists mainly of the following processes.1- Preparation of paint paste; mixing the pigment with enough binder in order to turn it into a cake of optimum consistency for the crushing process,2- Crushing the cake until a certain fineness is obtained in a suitable crushing machine,3- Mixing the crushed cake taken from the crushing machine with other ingredients in the prescription, adjusting the color and viscosity,4- Filtering the paint, filling the boxes and packaging.While each of these works can be done on separate devices, some of them can be done on the same device.The above processes are generally done on the machines listed below.1- Preparation of the Cake:Preparation of paint paste; It is made in either vertical or flat cake mixers or high speed gear-disc mixers.
a) Vertical and Slant Mixers:Mixing arms are low speed machines that are strong and very close to the walls of the device. Although there are various types of these mixers, there is no difference between them in terms of dispersion functions.Dimension sizes for calculating the volume of the mixer are determined and recorded.It is assumed that a cake (1), which can be filled up to 80% of the mixer volume and delivered to the crushing machine, can be prepared in an hour (the specific weight of the cake is also not taken into account).b) High Speed Gear-Disc Embedders: (Cewles Mill)They are mixers similar to coarse-toothed circular saws. In these mixers, it is assumed that the optimum diameter of the gear-disk to be calculated according to the formulas mentioned below can be mixed in a 3-fold box and a 2-fold height of a cylindrical cake mass in one hour. The specific weight of the cake is considered to be 1.2.Formula:0.0325 x D3 = 3.14 x (1.5 D) 2 x D x 1.2 x 8 x 300 x 0.80 / 1060.0325 x D3 = ... Tons / year Pie.Here;D = Optimum disc diameter (in cm.)The optimum diameter of the Gear-Disc is calculated by the formula below.
Here;G = Power of electric motor that rotates gear-disk (in horsepower)D = optimum diameter of the gear-disc (in cm).2- Crushing Paint Paste:The cake coming out of the cake preparation machine is crushed in the paint crushing machines listed below.a) Roller crushing machines,b) Ball mills (steel, porcelain and flint ball),c) Sand or bead crushers (Sand Mill, Pearl Mill),d) Pebbled-Attended dispersions,e) High speed disc mixers,f) Tapered chamber mills (Stone Mill),g) High speed stone mills,h) Colloid mills.a) Roller Crushing Machines:These are 1, 3, 5 roller rolls.It is assumed that the blade with the scraper blade in 5-roller rolls gives 0.48 grams per square centimeter, 0.24 grams in 3-roller rolls, and 0.12 grams in 1-roller rolls.Production accordingly:For 5-roller rolls;D x L x 0,217 = ... Tons / year Paint,For 3-roller rolls;D x L x 0.1085 = ... Tons / year Paint,For 1 cylinder rolls;D x L x 0,0542 = ... Ton / year Paint.D = The exact diameter of the roller with the scraping blade (cm.)L = Length of the cylinder with the scraping blade (cm.)The above calculations are for rolls with hydraulic and cooling equipment. The efficiency factor is 90% for mechanical rollers without a hydraulic device with a cooling device and 60% for mechanical rolls without a hydraulic and cooling device.
In this regard, the number of cylinders, cylinder diameter and cylinder length as well as the hydraulic and cooling device of the rolls are determined and recorded.b) Ball Mills (Steel, Porcelain or Pebble Ball):In these mills, the preparation, grinding and mixing of the crushed paste with other ingredients in the paint recipe can also be done. In this regard, other auxiliary machines are not sought in ball mills.
In the ball mills, the dimensions required to calculate the empty internal volume are determined and recorded.In these mills, it is assumed that 25% of the empty volume of the paint can be crushed in 8 hours and the specific weight of the paint is 1.2. Ball volumes are not deducted separately when calculating the empty internal volume of the mill.c) Beaded Mills (Pearl Mill): (Pressureless vertical single chamber, pressureless oblique single chamber, pressurized vertical multi chamber)
These consist of one or more chambers with a vertical or flat cylinder or square cross-section and a rotating shaft in the axis of this chamber or chambers, and a large number of specially shaped disks fixed on this shaft. It makes siliceous beads (pearl), where the discs put into the bowl and spinning at high speed give a great speed.
In pressurized, upright, multi-chambered, beaded mills, the pressure is first subjected to crushing a container in the first chamber with large beads, then fine beading in other fine-beaded chambers or chambers, grinding beads up to 85% of the chamber volume in single-chamber slant mills. The capacity of these two types of mills is 3.5 times the capacity of single-chamber single pressureless vertical pearl shafts in the same volume, and 4.5 times in single-chamber slant mills.
One-hour finished paint capacity, 21 times the total chamber volume in vertical multi-chamber pressure bead mills (6 x 3.5), 27 times the total chamber volume in flat-single chamber non-pressurized bead mills, 27 times (6 x 4.5) in vertical-single chamber unpressurized in bead mills, it is assumed to be 6 times the chamber volume. The specific weight of the paint is taken as 1.2. In addition, the efficiency factor is not taken into account.
d) Pebbled Atrium Dispersers:These consist of a cylindrical water-jacketed reservoir of wear-resistant material and several horizontal and perpendicular mixing arms rotating at high speed around a vertical axis therein. In these devices, the spindle rotating with a high speed makes the spheres (usually 10-12 mm in diameter) where the arms reach a great speed.
One hour paint capacity of these devices; half the volume of the chamber is considered and the dye specific gravity is taken as 1.2.In addition, an efficiency factor is not sought.However, the capacity for machines with a spare "Mill Reservoir" is multiplied by the factor 1.20. Only one "Milli-Hopper" is considered for each dispersant.
Measures needed are calculated and recorded to calculate the empty-inner volume of the chamber.e) High Speed Gear-Disc Mixers:These are mixers similar to coarse-toothed circular saws.However, there are also types with different disc shapes. These mixers are very suitable for the production of plastic emulsion paints and construction paints that do not require much finesse. If plastic emulsion paints are manufactured in these devices, it is assumed that a cylindrical paint mass at 3 times the height of the optimum diameter of the gear-disk calculated in accordance with the formulas below, and the specific gravity of the paint is 1.2.3.14 x (1.5 D) 2 x 2D x 1.2 x 8 x 300 x 0.80 / 106 = 0.0325 D30,0325 D3 = .... Tons / year Paint
Here;D = Optimum disc diameter (in cm.)The optimum diameter of the Gear-Disc is calculated by the formula below;
G = Power of electric motor turning gear-disk (in horsepower)D = optimum diameter of the gear-disc (in cm)In the same mixers, if other types of paints other than plastic emulsion paints are made, the charging time is considered to be 1.5 hours.In this case, the formula;0,0217 D3 = .... Tons / year Paint.f) Mills with Conical Chamber,g) High Speed Grinding Mills,h) Colloid Mills:The capacities of new devices that are not mentioned here and will be used in the future with these mills; It is determined with a stopwatch until its special criteria are determined.But; The preparation of the main raw materials in the form of pastry and crushing in the crushing machines will be determined under the supervision of the Expertise Committee. During these operations (by setting the crushing machine to 4.5 hegman in oil and plastic paints), the process that will take the most time in the chronometer is considered as the support for the capacity calculation.The same system is applied for zinc powder paints.In this case, according to the general production amount to be found with the stopwatch; Construction paints, dispersion paints and zinc powder based paints are determined from the declaration of the companies.
3- Mixing Crushed Paste with Other Substances in the Prescription Adjusting Color and Viscosity: Mixing the paste coming out of the crushing machine with the other ingredients in the recipe, adjusting the color and viscosity is done in mixers with a motor-driven (fixed or mobile) rotary shaft, with a pallet, propeller, turbine or disc mixer. It is assumed that a 3.7 HP mixer can mix 4 tons of paint per hour. However, these devices are not taken as narrow passages in manufacturing. However, the paint capacity determined in the enterprises that have no mixer and perform this operation manually is multiplied by the factor of 0,90.
4- Filtering the Paint, Filling the Boxes, Closing and Packing the Boxes:These processes are determined by chronometry.The above processes, production tools and capacity calculation methods and conditions are described; The raw and auxiliary compositions of cellulosic paints, plastic emulsion paints, oil paints and synthetic boilers are shown below.However, these compositions (due to the variety of materials and raw materials and qualities) refer to the weighted averages for all paint types.Cellulosic Paint Raw and Auxiliary Materials: (To obtain 100 kg. Product)Titan dioxide: 6 kg.- Inorganic pigments (except titanium dioxide): 3 kg.- Organic pigments: 3 kg.- Carbon black: 1 kg.- Nitrocellulose (dry): 16 kg.- Plasticizers (esters of mono and polyacids, phosphoric esters, castor oil, etc.): 7.5 kg.- Synthetic resins: 7 kg.- Alkyd resins (100%): 7 kg.- Ketones and ketone alcohols: 11 kg.- Esters: 15 kg.- Glycol ethers: 8 kg.- Alcohols (excluding industrial alcohol): 8 kg.- Industrial alcohol: 2 kg.- Toluol: 7 kg.- Xylol or toluol: 5 kg.- Aluminum and bronze cake or powder: 1 kg.Hexane-heptane: 3 kg.
These amounts include the average manufacturing loss.Cellulosic Leather Dyes Raw and Auxiliary Materials: (to obtain 100 kg. Product)Titan dioxide: 6 kg.- Inorganic pigments (except titanium dioxide): 5 kg.- Organic pigments: 3 kg.- Other organic dyes: 3 kg.- Carbon black: 10 kg.- Nitrocellulose (dry): 16 kg.- Plasticizers (esters of mono and polyacids, phosphoric esters, castor oil, etc.): 7.5 kg.- Synthetic resins: 7 kg.- Ketones and ketone alcohols: 10 kg.- Esters: 14 kg.- Glycol ethers: 7 kg.- Alcohols (excluding industrial alcohol): 7 kg.- Toluol: 6 kg.- Industrial alcohol: 2 kg.- Xylol or toluol: 4 kg.- Aluminum and bronze cake or powder: 1 kg.Hexane-heptane: 3 kg.These quantities include average manufacturing losses.Plastic Emulsion Paints Raw and Auxiliary Materials: (To obtain 100 kg. Product):- Synthetic resin emulsions and rubber latex (Polyvinyl acetate, acrylic, latex, etc. (52-55%): 55 kg.- Chemical additives: 4 kg.- Filling materials: 12 kg.- Carboxymethylcellulose: 3 kg.- Methyl cellulose, hydroxyethyl cellulose, methyl hydroxy propyl cellulose: 3 kg.Titan dioxide: 25 kg.- Organic pigments: 2 kg.- Inorganic pigments: 2 kg.- Carbon black: 1 kg.- Tansioactive substances: 0.3 kg.
Plastic-Emulsion Leather Dyes and Auxiliary Materials: (To obtain 100 kg of product):- Synthetic resin emulsions and rubber latex (Polyvinyl acetate, acrylic, latex etc. (52-55%)): 50 kg.- Chemical additives: 4 kg.- Filling materials: 5 kg.- Carboxymethylcellulose: 3 kg.Titan dioxide: 20 kg.- Organic pigments: 2 kg.- Direct and acid paints: 3 kg.- Inorganic pigments (excluding titanium dioxide): 5 kg- Carbon black: 5 kg.- Casein: 5 kg.- Tansioactive substances: 4 kg.- Candles (natural and synthetic): 5 kg.- Methyl cellulose, hydroxyethyl cellulose, methyl hydroxypropyl cellulose: 3 kg.The above quantities include average manufacturing losses.Construction Paints:Description: This type of paints is a group of paints, which are applied with a lot of brushes and rots in the painting of walls, wood, iron and steel surfaces in general constructions, drying under normal weather conditions and the types specified below.Types are:a) Oiled (linen oil, decorated, standoil)b) Varnished (rosin, phenolic resinous)c) Alkyd (alkyd resin)
NOTE: In this classification, plastic-emulsion paints and aluminum-based paints are excluded, faca paints and anticorrosive paints (cheesy and zinc chromated) are considered here.Raw and Auxiliary Materials: (To obtain 100 kg of product).- Alkyd resins and oil rosin: 45 kg.- Synthetic varnish: 5 kg.Titan dioxide: 20 kg.- Inorganic pigments (except titanium dioxide): 5 kg.- Organic pigments: 3 kg.- Black pigments: 2 kg.- Skaters: 2 kg.- Chemical additives: 3 kg.- Fillings: 10 kg.- Vayt sipirit: 6 kg.- Solvent naphtha: 2 kg.- Hexane, heptane: 2 kg.- Tensioactive substances: 0.3 kg.The above quantities include average manufacturing losses.Industrial Paints:Description: These paints are generally the type of paints that are dried in the air and in special ovens and are used in the painting of auto, auto assembly, home appliances and similar industrial products and applied with special apparatus.Raw and Auxiliary Materials: (To obtain 100 kg of product).- Alkyd resins: 20 kg.- Other synthetic varnishes (with rosin varnishes, excluding varnishes with resin from the fabric): 20 kg.Titan dioxide: 20 kg.- Inorganic pigments (except titanium dioxide): 5 kg.- Organic pigments: 3 kg.- Black pigments: 2 kg.- Chemical additives: 5 kg.- Alcohols (excluding industrial alcohol): 5 kg.- Industrial alcohol: 1 kg.- Xylol or toluol: 15 kg.- Vayt sipirit: 5 kg.- Solvent naphtha: 2 kg.- Hexane, heptane: 2 kg.- Tensioactive substances: 0.3 kg.These quantities include average manufacturing losses.CELLULOSIC PASTE AND CELLULOSIC PRIMER PAINTS MANUFACTURING
Capacity: These products are usually made in paint crushing machines. Capacity is determined according to the principles in oil and synthetic paints. Raw and Auxiliary Materials: a) Cellulosic Paste: (To obtain 100 kg of product) - Cellulosic varnish: 40 kg. Titan dioxide: 10 kg. - Color pigments (red iron oxide and carbon black): 10 kg. - Filling materials: 40 kg. - Plasticizers: 7 kg. b) Cellulosic Primer Paint: (To obtain 100 kg of product) - Cellulosic varnish: 60 kg. Titan dioxide: 10 kg. - Color pigments (red iron oxide and carbon black): 10 kg. - Filling materials: 20 kg. - Plasticizers: 7 kg. The above quantities include average manufacturing losses. ALUMINUM PAINTS-BRONZE PAINTS and PRODUCTION OF ALUMINUM BASED EFFECT PAINTS Capacity: For this type of manufacturing; The figure found by adding 25% development share to the largest of the actual production in the past three years is considered as the annual capacity of the facility. In facilities that have just started operation or have no actual consumption for other reasons, the capacity is compared to similar facilities and is appreciated. Aluminum Paint-Bronze Paint Raw and Auxiliary Materials: (To obtain 100 kg. Product) - Aluminum paste: 20 kg. - Bronze cake: 2 kg. - Synthetic resin (kumoron-inden-hydrocarbon resin etc.): 42 kg. - Solvent (xylol, toluol): 42 kg. These quantities include average manufacturing losses. Aluminum Based Effect Paint (Synthetic) Raw and Auxiliary Materials: (To obtain 100 kg. Product): - Aluminum paste: 5 kg. - Alkyd resin: 57 kg. - Melamine (50%): 20 kg. - Aromatic solvents: 15 kg. - Other solvents: 8 kg. - Butanol: 2 kg. - Silicone fluid: 0.2 kg. These quantities include average manufacturing losses. Aluminum Based Effect Paint (Cellulosic) Raw and Auxiliary Materials: (To obtain 100 kg. Product):
- Alüminyum pasta : 5 kg.
- Nitrosellüloz :15 kg.
- Alkid reçine : 20 kg.
- Sentetik reçineler : 7 kg.
- Plastifiyan : 5 kg.
- Solventler : 45 kg.
- Silikon fluid : 0,2 kg.
These quantities include average manufacturing losses.POISONOUS MARINE PAINTS MANUFACTURINGCapacity:Toxic marine paints are made in special devices with cooking-mixing method without crushing in crushing machines such as oil and synthetic paints.If it is made in paint crushing machines, the basis in oil and synthetic paints is applied.In the Cooking-Mixing method, the production is done in two stages:1- Preparation of special varnish,2- Preparation of the poisonous paint by mixing and mixing poisonous substances in the varnish in hot,Preparation of special varnish is carried out in closed boilers with a cover for loading raw materials with a heating device, mixer, control thermometer and aspirator.The preparation of the poisonous paint by adding poisonous substances to the varnish is done in mixing boilers with a heating device and a mixer.Both devices can be filled up to 80% of their volume, varnish production will take 8 hours including filling, cooking, draining, toxic paint manufacturing will take 6 hours including filling, cooking, draining, the specific gravity of the varnish D = 1, the toxic paint specific gravity D = 1 It is considered to be 2 and 40% by weight of varnish is added to the poisonous paint.The bottleneck is calculated according to the above principles and the capacity is specified only as an antifouling capacity. Since the antifouling paint varnish has no use alone, no capacity is calculated for the antifouling paint varnish.Raw and Auxiliary Materials: (To obtain 100 kg of product):- Synthetic resin: 20 kg.- Solvents: 16 kg.- Chemical additives: 6 kg.- Copper 1 Oxide and other poisons: 40 kg.- Lead toper: 8 kg.- Inorganic pigments (iron chrome oxide): 13 kg.These quantities include average manufacturing losses.
ALKIT AND POLYESTER RESIN MANUFACTURING (B. Y. K. Decision: 1991/336):Alkyd and polyester resins are made of stainless steel or thick nickel plated devices with motor-agitator, cooling jacket and serpentine, heating up to 2500 C, a thinning boiler with a volume of at least twice the volume of the reaction vessel. . 80% of the reaction vessel volume will be charged, and in the production of alkyd resin 1 to 1.5 a day; It is accepted that 1.5-2 charge production per day can be produced in charge polyester production.
In facilities where thinning boiler is not sufficient, a working efficiency of 85% is also taken into account. In facilities where the thinning boiler is not available and thinning is done in the reaction boiler, it is assumed that 50% of the reaction boiler will be charged, and a working efficiency of 85% is considered. Density is considered 1.30 for alkyd and 1.30 for polyester. If two productions are made in the same facility, how many days of the year is alkyd and polyester is determined from the company declarations.
The capacity is shown as 100% alkyd and polyester.Polyester Resin Raw and Auxiliary Materials:(For 100 kg. 100% Resin Production and subsequently thinning it to 60%):
- Polyalcohols: 45 kg.
- Phthalic anhydride and other polyacids: 65 kg
. - Mono acids: 2 kg.
- Monomers (Butylacrylate, methyl methacrylate, Acrylonitrile etc.): 8 kg.
- Other chemicals: 8 kg.
- Xylol or toluol: 5 kg.
- Citiren: 55 kg.
- Alcohols: 2 kg.
- Organic peroxides: 4 kg.
- Beeswax, paraffin wax and hydrogenated castor oil: 1 kg.
Alkyd and polyester resins are made of stainless steel or thick nickel plated devices with motor-agitator, cooling jacket and serpentine, heating up to 2500 C, a thinning boiler with a volume of at least twice the volume of the reaction vessel. . 80% of the reaction vessel volume will be charged, and in the production of alkyd resin 1 to 1.5 a day; It is accepted that 1.5-2 charge production per day can be produced in charge polyester production.
In facilities where thinning boiler is not sufficient, a working efficiency of 85% is also taken into account. In facilities where the thinning boiler is not available and thinning is done in the reaction boiler, it is assumed that 50% of the reaction boiler will be charged, and a working efficiency of 85% is considered. Density is considered 1.30 for alkyd and 1.30 for polyester. If two productions are made in the same facility, how many days of the year is alkyd and polyester is determined from the company declarations.
The capacity is shown as 100% alkyd and polyester. Polyester Resin Raw and Auxiliary Materials: (For 100 kg. 100% Resin Production and subsequently thinning it to 60%):
- Polyalcohols: 45 kg.
- Phthalic anhydride and other polyacids: 65 kg.
- Mono acids: 2 kg.
- Monomers (Butylacrylate, methyl methacrylate, Acrylonitrile etc.): 8 kg.
- Other chemicals: 8 kg.
- Xylol or toluol: 5 kg.
- Citiren: 55 kg.
- Alcohols: 2 kg.
- Organic peroxides: 4 kg.
- Beeswax, paraffin wax and hydrogenated castor oil: 1 kg
Alkyd Resin Raw and Auxiliary Materials: (For 100 kg. 100% Resin Production and subsequently thinning it to 60%):
- Oils and industrial fatty acids: 55 kg.
- Glycerin and other polyalcohols: 22 kg.
- Phthalic anhydride: 27 kg.
- Polyacids: 3 kg. - Mono acids: 3 kg.
- Synthetic resins: 4 kg.
- Chemical additives: 1 kg.
- Wow spirit (solvent 140/210) and xylol or toluol: 67 kg.
If special solvents such as alcohols, styrene and solvent naphtha are used in manufacturing, the solvent can be added to the report by deducting from 140/210 or xylol.
The items covered by the items with the group name in the recipes are described below.
Alcohols:
(Methyl, isopropyl, butyl, isobutyl alcohols, methyl isobutyl carbinol, methoxy butanol etc.)
Ketones and Ketone-Alcohols:
(Acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, methyl cyclohexanone, diacetone alcohol, isoporon, pentoxone etc.)
Esters:
(Methyl acetate, ethyl acetate, isopropyl acetate, butyl acetate, amylasetate, methyl amyl acetate, ethyl lakate, ethylene glycol, monoethyl ether acetate, methoxy butanol acetate, methyl cyclohexyl acetate, isopropyl oxytol acetate.)
Glycol Ethers:
(Mono methyl, mono methyl mono butyl and mono phenyl ethers of ethylene glycol and diethylene glycol, etc.)
Softeners:
(Dimethyl, diethyl, dibutyl, dioctyl, butyl benzyl and dibutyl glycol, dimethyl cyclohexanol, diphenyl, dimethylglycol phthalates, tributyl, triphenyl, tritoyl, trichloro, trichloretyl phosphates, tributyl citrate, dibutyl tartrate, and sebacetyl adenocyl acetate butyl stearate, methyl abietate, triacetin, dimethyl cyclohexanol oxolate, camphor, chlorinated paraffins, chlorinated diphenyls, castor oil, triacetyl glyceryl monolactate, acetyl triethyl citrate, ethyl phthalyl ethyl glycolate, etc.)
Polyalcohols:
(Pentaeritrit, dipentaeritrit, trimethylol ethane, trimethylol propane, sorbitol, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, dipropylene glycol, neopantylene glycol, etc.)
Poly Acids:
(Phthalic anhydride malaic anhydride inizetallic fumaric azelaic succinic thread and sebacic oxalic chlorendic acids etc.)
Mono Acids:
(Fatty acids, tall oil fatty acids, synthetic fatty acids, pelargonic acid, isodonoic acid, isooctanoic, 2-ethyl hexanoic acid, P-tert benzoic acid, etc.)
Synthetic Resins:
(Condensation, polycondensation, polyaddition preparations, polymerization and copolymerization preparations, artificial resins obtained by esterification of natural resins and resin acids, chemical derivatives of natural rubber, cellulose acetate, acetate, acetebrate, ethyl cellulose, etc.)
Chemical Additives:
(Lecithin, dipentene, pine oil, phenol, cresol, guacocol, oximes, zinc resate and zaftenate, methyl methacrylate, acrylo nitrile, hydroquinone, P-tert butyl hydroquinone, methyl hydroquinone, butyl catechol, aeak bactericidal chemicals, morpholine, aluminum stearate, sodium phenol phenate, pentaks phenol sodium salt, silicones etc.)
It is sufficient to show these explanations only in table 4.In addition, calcium and aluminum silicate, silicium dioxide and natural aluminum silicate can be given by cutting from glass, ball and cromanite ball for pearlmiller, and silica fossils and fillers activated for filtering and decolouring.
STANDOIL BEZIR PRODUCTION:
Capacity:
Standoil production can be done exclusively in closed boilers with fittings suitable for heating up to 300 degrees.
Filling, Cooking, Cooling and Discharging Time:
a) 16 hours in facilities with cooling jacket or coil and filling-discharge pump or pressurized gas system, b) 20 hours only in facilities with cooling jacket or serpentine, c) 28 hours only in facilities with filling-discharge pump or pressurized gas system, d) In facilities that do not have any of these equipment and equipment, they are considered as 32 hours.Cooking capacity in boilers with or without spare overflow boiler; It is considered to be 80% of the volume of the cooking vessel. Calculating the volume of the boiler, it is determined and recorded whether there is a cooling and filling-unloading device with the necessary measures.Raw and Auxiliary Materials: (To obtain 100 kg of product)
- Refined flax oil: 110 kg. or- Refined flax oil: 84 kg.- Refined soybean oil: 26 kg.
The above quantities include average manufacturing losses.
SHOE PAINT AND VARIOUS POLISHING MANUFACTURERS1-Shoe polish and shoe polish are usually prepared in copper and galvanized hair boilers.2-In determining the capacity, the measurements that are the basis for calculating the boiler volume are taken and it is accepted that 80% of the volume will be filled by calculating the volume.
3-Preparation, boiling and filling period is accepted for 4 hours. Compared to this, in such production, it is calculated by considering that the boilers will be charged 2 times a day.4- Since preparation and filling is based on hand workmanship, 70% efficiency is also accepted.Formula: V x 2 x 0.8 x 0.7 = ... manufacture in 8 hours.Formula: 5 x 1.12 - 8 hour manufacturing.
(V = Boiler volume) V x 336 = ... tons / year
5- Raw materials:a) Shoe polishParaffin: 6.5%Monton: 12%Other chemicals: 6%
b) Polishes
Paraffin: 20%
Cauliflower: 10%
Wax: 10%
Solvent: 65%